Bianca Di Angelo and Frey (Freyanca)
I think these two might go well together apart from the age difference though.
Money Maker and Jason Grace (Jasney)
This could work, if they both were not dead of course.
Ethan Nakamura and Georgina (Ethina)
If Ethan was not evil and georgina was a little older than yeah but for now
Austin Lake and Chuck Hedge (Chuckstin)
I could definitely see Austin as Chuck's babysitter but not as a couple so...